5. Don Cheadle as War Machine (Iron Man and Captain America, 2010-2016)
Ignore the plastic surgery Rhodey must have gotten between Iron Man and Iron Man 2 to make him look more like Don Cheadle instead of Terrence Howard, War Machine is one of the many compelling characters the MCU has to offer. Cheadle sells every minute of it as well, gliding into the role with ease in the second Iron Man.
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