10. Angelina Jolie & Billy Bob Thornton
Married 2000-2003
Thornton has said of his marriage with Jolie that he blew it out of insecurity.
"We had a great time together," he told ABC News. "We had a great marriage and I chickened out because I didn't feel good enough. That's all that happened. It was no big deal, we never hated each other."


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